Selective Oxidation of Alcohols by Orthorhombic Mo-V-O Phase with Molecular Oxygen

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著者

    • WANG Feng
    • CREST, Japan Science and Technology Corporation (CREST-JST)

抄録

We have investigated heterogeneous oxidation of alcohols using crystalline molybdenum vanadium oxide (Mo–V–O) as catalyst with molecular oxygen as oxidant. The major product from primary alcohol was aldehyde, the secondary alcohol was mainly dehydrated to olefin, and the oxidation of cyclic alcohols chiefly afforded ketones. A Hammett plot suggested that hydride abstraction might be involved in the reaction step. We have discussed possible reaction mechanism based on substrate adsorption and activation on catalytically active sites.

収録刊行物

  • Chemistry letters

    Chemistry letters 37(2), 184-185, 2008-02-05

    The Chemical Society of Japan

参考文献:  21件中 1-21件 を表示

  • <no title>

    STEINHOFF B. A.

    J. Am. Chem. Soc. 128, 4348, 2006

    被引用文献1件

  • <no title>

    TSUNOYAMA H.

    J. Am. Chem. Soc. 127, 9374, 2005

    被引用文献1件

  • <no title>

    XAMENA F. X. L.

    J. Catal. 250, 294, 2007

    被引用文献1件

  • <no title>

    ABAD A.

    Tetrahedron 62, 6666, 2006

    被引用文献1件

  • <no title>

    SON Y.-C.

    Angew. Chem., Int. Ed. 40, 4280, 2001

    被引用文献1件

  • <no title>

    SADAKANE M.

    Angew. Chem., Int. Ed. 46, 1493, 2007

    被引用文献1件

  • <no title>

    UEDA W.

    Top. Catal. 38, 261, 2006

    被引用文献1件

  • <no title>

    MIZUNO N.

    Surface and Nanomolecular Catalysis, 2006

    被引用文献1件

  • <no title>

    UEDA W.

    Top. Catal. 38, 261, 2006

    被引用文献1件

  • <no title>

    CONNERS K. A.

    Chemical Kinetics, The Study of Reaction Rates in Solution, 1990

    被引用文献1件

  • <no title>

    http://www.csj.jp/journals/chem-lett/index.html

    被引用文献1件

  • <no title>

    ARAMENDIA M. A.

    Catal. Lett. 58, 53, 1999

    被引用文献1件

  • <no title>

    YAMAGUCHI K.

    J. Am. Chem. Soc. 122, 7144, 2000

    被引用文献11件

  • <no title>

    YAMAGUCHI K.

    Angew. Chem., Int. Ed. 41, 4538, 2002

    被引用文献10件

  • <no title>

    ISHIDA T.

    Angew. Chem., Int. Ed. 46, 7154, 2007

    被引用文献6件

  • <no title>

    CHOUDARY B. M.

    Angew. Chem., Int. Ed. 40, 763, 2001

    被引用文献2件

  • <no title>

    NEUMANN R.

    J. Org. Chem. 56, 5707, 1991

    被引用文献1件

  • <no title>

    FUJIBAYASHI S.

    J. Mol. Catal. A : Chem. 110, 105, 1996

    被引用文献2件

  • <no title>

    BRIAND L. E.

    Appl. Catal. A 256, 37, 2003

    被引用文献3件

  • <no title>

    UEDA W.

    Catal. Today 99, 43, 2005

    被引用文献1件

  • <no title>

    HANSCH C.

    Chem. Rev. 91, 165-195, 1991

    被引用文献11件

各種コード

  • NII論文ID(NAID)
    10021077566
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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