Selective Oxidation of Alcohols by Orthorhombic Mo-V-O Phase with Molecular Oxygen

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著者

    • WANG Feng
    • CREST, Japan Science and Technology Corporation (CREST-JST)

抄録

We have investigated heterogeneous oxidation of alcohols using crystalline molybdenum vanadium oxide (Mo–V–O) as catalyst with molecular oxygen as oxidant. The major product from primary alcohol was aldehyde, the secondary alcohol was mainly dehydrated to olefin, and the oxidation of cyclic alcohols chiefly afforded ketones. A Hammett plot suggested that hydride abstraction might be involved in the reaction step. We have discussed possible reaction mechanism based on substrate adsorption and activation on catalytically active sites.

収録刊行物

  • Chemistry letters  

    Chemistry letters 37(2), 184-185, 2008-02-05 

    The Chemical Society of Japan

参考文献:  21件

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各種コード

  • NII論文ID(NAID)
    10021077566
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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