Fluoride Complexation of Element 104, Rutherfordium (Rf), Investigated by Cation-exchange Chromatography

• Ishii Yasuo

  Advanced Science Research Center, Japan Atomic Energy Agency (JAEA) Radiochemical Research Laboratory, Shizuoka University

• Toyoshima Atsushi

  Advanced Science Research Center, Japan Atomic Energy Agency (JAEA)

• Tsukada Kazuaki

  Advanced Science Research Center, Japan Atomic Energy Agency (JAEA)

• Asai Masato

  Advanced Science Research Center, Japan Atomic Energy Agency (JAEA)

• Toume Hayato

  Advanced Science Research Center, Japan Atomic Energy Agency (JAEA)

• Nishinaka Ichiro

  Advanced Science Research Center, Japan Atomic Energy Agency (JAEA)

• Nagame Yuichiro

  Advanced Science Research Center, Japan Atomic Energy Agency (JAEA)

• Miyashita Sunao

  Radiochemical Research Laboratory, Shizuoka University

• Mori Tomotaka

  Radiochemical Research Laboratory, Shizuoka University

• Suganuma Hideo

  Radiochemical Research Laboratory, Shizuoka University

• Haba Hiromitsu

  Nishina Center for Accelerator Based Science, RIKEN

• Sakamaki Masami

  Department of Chemistry, Niigata University

• Goto Shin-ichi

  Department of Chemistry, Niigata University

• Kudo Hisaaki

  Department of Chemistry, Niigata University

• Akiyama Kazuhiko

  Graduate School of Science and Engineering, Tokyo Metropolitan University

• Oura Yasuji

  Graduate School of Science and Engineering, Tokyo Metropolitan University

• Nakahara Hiromichi

  Graduate School of Science and Engineering, Tokyo Metropolitan University

• Tashiro Yuki

  Graduate School of Science, Osaka University

• Shinohara Atsushi

  Graduate School of Science, Osaka University

• Schädel Matthias

  Gesellschaft für Schwerionenforschung

• Brüchle Willy

  Gesellschaft für Schwerionenforschung

• Pershina Valeria

  Gesellschaft für Schwerionenforschung

• Kratz Jens V.

  Institut für Kernchemie, Universität Mainz

抄録

We report on new and much more precise cation-exchange data of element 104, rutherfordium (Rf), in the fluoride ion concentration [F⁻] range of 5.29×10⁻⁵−1.04×10⁻³ M. The result based on one-atom-at-a-time chemistry clearly demonstrates that the distribution coefficients (K_d) decrease with increasing [F⁻], suggesting successive fluoride complexation of Rf. The complexation of Rf is briefly discussed in terms of fully relativistic density functional calculation theory.

収録刊行物

• Chemistry Letters

  Chemistry Letters 37 (3), 288-289, 2008

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390282679561877376
• NII論文ID: 10021078356
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2008.288
• COI: 1:CAS:528:DC%2BD1cXjsFCiu7k%3D
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/37/3/288/55597766/cl.2008.288.pdf
• 本文言語コード: en
• データソース種別:
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  • CiNii Articles
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