Dynamics of Polymer Chains in Porous Thin Films Prepared by Layer-by-layer Assembly of Isotactic Poly(methyl methacrylate) and Syndiotactic Poly(methacrylic acid)

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著者

    • KAMEI Daisuke
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University
    • AJIRO Hiroharu
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University
    • HONGO Chizuru
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University
    • AKASHI Mitsuru
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University

抄録

Using X-ray diffraction (XRD) analysis, the porous structure of isotactic (<I>it</I>-) poly(methyl methacrylate) (PMMA) thin films fabricated with layer-by-layer (LbL) assembly of <I>it</I>-PMMA and syndiotactic (<I>st</I>-) poly(methacrylic acid) (PMAA) was observed for the first time. The XRD patterns of crystalline <I>it</I>-PMMA on a substrate changed when the surrounding <I>st</I>-PMAA eluted out and was incorporated. These results indicate that the polymer chains of <I>it</I>-PMMA moved at the solid–liquid interface.

収録刊行物

  • Chemistry letters  

    Chemistry letters 37(3), 332-333, 2008-03-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021078724
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  CJP引用  J-STAGE 
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