A Two-step and Hysteretic Spin-crossover Transition in New Cyano-bridged Hetero-metal Fe^<II>Au^I 2-Dimensional Assemblage

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A new hetero-metal 2-dimensional (2D) spin-crossover complex, {[Fe<SUP>II</SUP>(3-Fpy)<SUB>2</SUB>][Au<SUP>I</SUP>(CN)<SUB>2</SUB>]<SUB>2</SUB>}<I><SUB>n</SUB></I> (3-Fpy = 3-fluoropyridine) has been synthesized and characterized crystallographically and magnetically. The complex consists of an octahedral Fe<SUP>II</SUP> ion and a mononuclear [Au<SUP>I</SUP>(CN)<SUB>2</SUB>]<SUP>−</SUP> unit with a linear coordination geometry which combine to form an infinite 2D structure. The spin transition observed for this complex is accompanied by a drastic and reversible change of color from blue to purple.

収録刊行物

  • Chemistry letters

    Chemistry letters 37(4), 422-423, 2008-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021079487
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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