Novel Sulfur–Selenium Exchange in Ethylenedioxy- and Ethylenedithio-dithiadiselenafulvalenedithiolates

• Toshiki Hayashi

  Department of Chemistry, Graduate School of Science, Osaka Prefecture University

• Xunwen Xiao

  Department of Chemistry, Graduate School of Science, Osaka Prefecture University

• Yuhta Yamaji

  Department of Chemistry, Graduate School of Science, Osaka Prefecture University

• Hideki Fujiwara

  Department of Chemistry, Graduate School of Science, Osaka Prefecture University

• Toyonari Sugimoto

  Department of Chemistry, Graduate School of Science, Osaka Prefecture University

• Hiroyuki Nakazumi

  Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University

Abstract

Ethylenedioxy- and ethylenedithiodithiadiselenafulvalenedithiolates are subjected to sulfur–selenium exchange, in which one selenium atom in the molecular skeleton is replaced by an outside sulfur atom. The reaction of the exchanged dithiolates with 2-methylthio-1,3-dithiolylium ion gives the corresponding thioquinone-1,3-dithiolemethides as new donor molecules.

Journal

• Chemistry Letters

  Chemistry Letters 37 (4), 428-429, 2008-03-08

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360565169064563456
• NII Article ID: 10021079535
• NII Book ID: AA00603318
• DOI: 10.1246/cl.2008.428
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/37/4/428/55596776/cl.2008.428.pdf
• Data Source:
  • Crossref
  • CiNii Articles