Novel Oxidative Generation of Ammonium Ylides and the Subsequent Silicon Polonovski Reaction
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- Honda Kiyoshi
- Graduate School of Engineering, Yokohama National University
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- Shibuya Hiromasa
- Graduate School of Engineering, Yokohama National University
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- Hoshino Yujiro
- Graduate School of Environment and Information Sciences, Yokohama National University
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- Inoue Seiichi
- Graduate School of Environment and Information Sciences, Yokohama National University
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We have demonstrated a novel oxidative generation of ammonium ylides by employing allylic amines having a silyl group. Treatment of N-(α-silylmethyl)-N-allylic amines with an oxidant, followed by acetic anhydride, brought about a tandem Brook rearrangement/silicon Polonovski reaction via the generation of ammonium ylides to give the corresponding amides, whereas the reaction of N-(α-cyano-α-silylmethyl)-N-allylic amines with an oxidant afforded the corresponding formamides.
収録刊行物
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- Chemistry Letters
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Chemistry Letters 37 (4), 442-443, 2008
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679562261248
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- NII論文ID
- 10021079662
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可