Novel Oxidative Generation of Ammonium Ylides and the Subsequent Silicon Polonovski Reaction

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著者

    • HONDA Kiyoshi
    • Graduate School of Engineering, Yokohama National University
    • HOSHINO Yujiro
    • Graduate School of Environment and Information Sciences, Yokohama National University
    • INOUE Seiichi
    • Graduate School of Environment and Information Sciences, Yokohama National University

抄録

We have demonstrated a novel oxidative generation of ammonium ylides by employing allylic amines having a silyl group. Treatment of <I>N</I>-(α-silylmethyl)-<I>N</I>-allylic amines with an oxidant, followed by acetic anhydride, brought about a tandem Brook rearrangement/silicon Polonovski reaction via the generation of ammonium ylides to give the corresponding amides, whereas the reaction of <I>N</I>-(α-cyano-α-silylmethyl)-<I>N</I>-allylic amines with an oxidant afforded the corresponding formamides.

収録刊行物

  • Chemistry letters  

    Chemistry letters 37(4), 442-443, 2008-04-05 

    The Chemical Society of Japan

参考文献:  18件

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各種コード

  • NII論文ID(NAID)
    10021079662
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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