Self-assembly-directed Spin Conversion of Iron(II) 1,2,4-Triazole Complexes in Solution and Their Effect on Photorelaxation Processes of Fluorescent Counter Ions
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Lipophilic, linear iron(II) 1,2,4-triazole complexes with 9,10-dimethoxyanthracene-2-sulfonate and 1-pyrenesulfonate counter ions are newly developed. These complexes are dispersed in toluene as nanofibers and display dynamic spin conversion characteristics. Photorelaxation process of 1-pyrenesulfonate accumulated on the complex is regulated depending on the spin state of iron(II) triazole complexes.
- Chemistry Letters
Chemistry Letters 37(4), 446-447, 2008-04-05
The Chemical Society of Japan