A Thiacalix[3]pyridine Copper(I) Complex as a Highly Active Catalyst for the Olefin Aziridination Reaction

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著者

    • TSUKAHARA Yuhei
    • Department of Material Science, Graduate School of Science, Osaka City University
    • HIROTSU Masakazu
    • Department of Material Science, Graduate School of Science, Osaka City University
    • HATTORI Shin-ichi
    • Department of Material Science, Graduate School of Science, Osaka City University
    • USUKI Yoshinosuke
    • Department of Material Science, Graduate School of Science, Osaka City University
    • KINOSHITA Isamu
    • Department of Material Science, Graduate School of Science, Osaka City University

抄録

A copper(I) complex with thiacalix[3]pyridine, [Cu(Py<SUB>3</SUB>S<SUB>3</SUB>)]<SUB>2</SUB>(PF<SUB>6</SUB>)<SUB>2</SUB>, is a competent catalyst for aziridination of olefins. The reaction of styrene (1 equiv) with PhI=NTs (1 equiv) at 20 °C produced <I>N</I>-(<I>p</I>-toluenesulfonyl)-2-phenylaziridine (71%, turnover number = 55) in the presence of 1.2 mol % catalyst under aerobic conditions. The turnover number increased up to 350 with a 0.12 mol % catalyst and a 5:1 styrene/PhI=NTs ratio in 41% yield.

収録刊行物

  • Chemistry letters

    Chemistry letters 37(4), 452-453, 2008-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021079750
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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