Convenient Synthesis of Angular Triquinane from 4-Alkenylfulvene via Thermal Cycloaddition Followed by Skeletal Rearrangement of the Resulting [4 + 2] Adduct

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著者

    • INAGAKI Sho
    • Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui
    • IMURA Keisuke
    • Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui
    • MORITA Toshio
    • Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui
    • YOSHIMI Yasuharu
    • Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui
    • HATANAKA Minoru
    • Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui

抄録

Alkenylfulvene prepared by the annulation of allylidenetriphenylphosphorane with 1,4-ynedione proceeded thermal cycloaddition in a highly regio- and stereoselective manner to give [4 + 2] adduct which was then converted into triquinane derivative by the treatment with LHMDS-<I>t</I>-BuOK after hydrolysis of the enol ether group.

収録刊行物

  • Chemistry letters  

    Chemistry letters 37(4), 454-455, 2008-04-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021079780
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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