Syntheses and Properties of Thiophene-inserted [3]Dendralenes with Redox-active 1,3-Dithiol-2-ylidene Units

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著者

    • HASEGAWA Masashi
    • Department of Applied Chemistry, Graduate School of Engineering, Ehime University
    • FUJIOKA Atsushi
    • Department of Applied Chemistry, Graduate School of Engineering, Ehime University
    • KUBO Takashi
    • Department of Applied Chemistry, Graduate School of Engineering, Ehime University
    • HONDA Tomohito
    • Department of Applied Chemistry, Graduate School of Engineering, Ehime University
    • MIYAMOTO Hisakazu
    • Department of Applied Chemistry, Graduate School of Engineering, Ehime University
    • MISAKI Yohji
    • Department of Applied Chemistry, Graduate School of Engineering, Ehime University

抄録

Novel dendralene type cross-conjugate molecules based on 1,3-dithiol-2-ylidene units with thiophene have been prepared. The conjugation in the oxidized stage is mainly through the thiophene core, while the cross-conjugated nature is observed in the neutral state. The CT complex of <B>2a</B> with TCNQF<SUB>4</SUB> shows moderated electrical conductivity of 10<SUP>−4</SUP> S cm<SUP>−1</SUP>.

収録刊行物

  • Chemistry letters

    Chemistry letters 37(4), 474-475, 2008-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021079941
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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