Reversible Single Crystal-to-Amorphous Phase Transition upon Dehydration-Rehydration and Associated Magnetism in [Mn^<II>(enH)(H_2O)][Cr^<III>(CN)_6]・H_2O

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著者

    • YOSHIDA Yusuke
    • Department of Chemistry and Institute for Advanced Materials Research, Hiroshima University
    • INOUE Katsuya
    • Department of Chemistry and Institute for Advanced Materials Research, Hiroshima University
    • KURMOO Mohamedally
    • Laboratoire de Chimie de Coordination Organique, CNRS-UMR7140, Universite Louis Pasteur

抄録

We report the rare occurrence of a reversible loss of crystallinity upon dehydration and regain upon rehydration by in situ X-ray diffraction on a single crystal of [Mn<SUP>II</SUP>(enH)(H<SUB>2</SUB>O)][Cr<SUP>III</SUP>(CN)<SUB>6</SUB>]·H<SUB>2</SUB>O and the associated thermal and magnetic properties characterized by an increase of the Curie temperature of the soft ferrimagnet from 42 to 75 K.

収録刊行物

  • Chemistry letters  

    Chemistry letters 37(5), 504-505, 2008-05-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021080203
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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