Reversible Single Crystal-to-Amorphous Phase Transition upon Dehydration–Rehydration and Associated Magnetism in [MnII(enH)(H2O)][CrIII(CN)6]·H2O

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  • Yusuke Yoshida
    Department of Chemistry and Institute for Advanced Materials Research, Hiroshima University
  • Katsuya Inoue
    Department of Chemistry and Institute for Advanced Materials Research, Hiroshima University
  • Mohamedally Kurmoo
    Laboratoire de Chimie de Coordination Organique, CNRS-UMR7140, Université Louis Pasteur, Institut Le Bel

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Abstract

<jats:title>Abstract</jats:title> <jats:p>We report the rare occurrence of a reversible loss of crystallinity upon dehydration and regain upon rehydration by in situ X-ray diffraction on a single crystal of [MnII(enH)(H2O)][CrIII(CN)6]·H2O and the associated thermal and magnetic properties characterized by an increase of the Curie temperature of the soft ferrimagnet from 42 to 75 K.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 37 (5), 504-505, 2008-03-29

    Oxford University Press (OUP)

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