1,3-Digermabicyclo[1.1.0]butane with an Inverted Bridge Ge–Ge σ Bond

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  • Takeaki Iwamoto
    Research and Analytical Center for Giant Molecules, Graduate School of Science, Tohoku University
  • Dongzhu Yin
    Department of Chemistry, Graduate School of Science, Tohoku University
  • Sven Boomgaarden
    Department of Chemistry, Graduate School of Science, Tohoku University
  • Chizuko Kabuto
    Research and Analytical Center for Giant Molecules, Graduate School of Science, Tohoku University
  • Mitsuo Kira
    Department of Chemistry, Graduate School of Science, Tohoku University

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<jats:title>Abstract</jats:title> <jats:p>1,3-Digermabicyclo[1.1.0]butane 2 was synthesized as yellow crystals. The molecular structure, 13C NMR and UV–vis spectra, and theoretical calculations have revealed that 2 is a typical long bond isomer, similarly to the silicon congener 1. Structural comparison between 1 and 2 is achieved.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 37 (5), 520-521, 2008-04-12

    Oxford University Press (OUP)

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