1,3-Digermabicyclo[1.1.0]butane with an Inverted Bridge Ge-Ge σ Bond

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著者

    • IWAMOTO Takeaki
    • Research and Analytical Center for Giant Molecules, Graduate School of Science, Tohoku University
    • YIN Dongzhu
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • KABUTO Chizuko
    • Research and Analytical Center for Giant Molecules, Graduate School of Science, Tohoku University
    • KIRA Mitsuo
    • Department of Chemistry, Graduate School of Science, Tohoku University

抄録

1,3-Digermabicyclo[1.1.0]butane <B>2</B> was synthesized as yellow crystals. The molecular structure, <SUP>13</SUP>C NMR and UV–vis spectra, and theoretical calculations have revealed that <B>2</B> is a typical long bond isomer, similarly to the silicon congener <B>1</B>. Structural comparison between <B>1</B> and <B>2</B> is achieved.

収録刊行物

  • Chemistry letters

    Chemistry letters 37(5), 520-521, 2008-05-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021080340
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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