Kinetic Studies on Complexation Reactions of Lithium Ion with Cryptand C211 in Ionic Liquids by Using ^7Li NMR

この論文にアクセスする

この論文をさがす

著者

    • SHIRAI Atsushi
    • Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology
    • IKEDA Yasuhisa
    • Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology

抄録

Kinetic studies on complexation reactions of Li<SUP>I</SUP> with cryptand C211 in <I>N</I>,<I>N</I>-diethyl-<I>N</I>-methyl-<I>N</I>-(2-methoxyethyl)ammonium bis(trifluoromethylsulfonyl)imide (DEMETFSI) and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMITFSI) have been carried out using <SUP>7</SUP>Li NMR. It was found that the reaction rates in both solutions depend on concentrations of free Li<SUP>I</SUP> and that their kinetic parameters are almost same. From these results, it is proposed that the Li<SUP>I</SUP> complexation reactions in DEMETFSI and EMITFSI solutions proceed though bimolecular mechanism.

収録刊行物

  • Chemistry letters

    Chemistry letters 37(5), 552-553, 2008-05-05

    The Chemical Society of Japan

参考文献:  22件中 1-22件 を表示

  • <no title>

    ROGERS R. D. ed.

    Green Industrial Applications of Ionic Liquids, 2000

    被引用文献1件

  • <no title>

    WASSERSCHEID P. ed.

    Ionic Liquids in Synthesis, 2003

    被引用文献1件

  • <no title>

    SEKI S.

    J. Phys. Chem. B 110, 10228, 2006

    被引用文献1件

  • <no title>

    MATSUMOTO H.

    J. Power Sources 160, 1308, 2006

    被引用文献1件

  • <no title>

    SATO T.

    J. Power Sources 138, 253, 2004

    被引用文献1件

  • <no title>

    WEBER C. F.

    Angew. Chem., Int. Ed. 44, 6033, 2005

    被引用文献1件

  • <no title>

    ILLNER P.

    Chem. Commun., 2007

    被引用文献1件

  • <no title>

    SHCHORI E.

    J. Am. Chem. Soc. 93, 7133, 1971

    被引用文献1件

  • <no title>

    UMEBAYASHI Y.

    J. Phys. Chem. B 111, 13028, 2007

    被引用文献1件

  • <no title>

    EARLE M. J.

    Pure Appl. Chem. 72, 1391, 2000

    被引用文献13件

  • Room-temperature ionic liquids, solvents for synthesis and catalysis

    WELTON T.

    Chem. Rev. 99, 2071-2083, 1999

    被引用文献92件

  • <no title>

    CHUN S.

    Anal. Chem. 73, 3737, 2001

    被引用文献15件

  • <no title>

    LUO H.

    Anal. Chem. 76, 2773, 2004

    被引用文献1件

  • <no title>

    SATO T.

    Electrochim. Acta 49, 3603, 2004

    被引用文献7件

  • <no title>

    CAHEN Y. M.

    J. Phys. Chem. 79, 1292, 1975

    被引用文献1件

  • <no title>

    SHAMSIPUR M.

    J. Phys. Chem. 90, 5997, 1986

    被引用文献1件

  • <no title>

    CERASO J. M.

    J. Phys. Chem. 81, 760, 1977

    被引用文献1件

  • <no title>

    LINCOLN S. F.

    J. Am. Chem. Soc. 108, 8134, 1986

    被引用文献1件

  • <no title>

    MEI E.

    J. Am. Chem. Soc. 99, 6532, 1977

    被引用文献1件

  • <no title>

    SHAMSIPUR M.

    J. Phys. Chem. 91, 447, 1987

    被引用文献1件

  • <no title>

    COX B. G.

    J. Am. Chem. Soc. 100, 4746, 1978

    被引用文献1件

  • Kinetic applications of NMR spectroscopy

    LINCOLN S. F.

    Progr. Reac. Kinet. 9, 1-91, 1977

    被引用文献2件

各種コード

  • NII論文ID(NAID)
    10021080683
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
ページトップへ