Mechanical Stirring Speed in Water/Hexane Biphasic Catalyst Controls Regioselectivity of Pd-catalyzed Allylation Reaction
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Vigorous mechanical mixing of the water/hexane biphasic Pd-catalyzed allylation of benzenethiol gave sterically congested allyl sulfides, due to high reactivity of the enforced orientation of the η<SUP>1</SUP>-allylpalladium intermediate at the solvent interface.
- Chemistry Letters
Chemistry Letters 37(6), 640-641, 2008-06-05
The Chemical Society of Japan