Phenyltellanyl Triflate (PhTeOTf) as a Powerful Tellurophilic Activator in the Friedel–Crafts Reaction

• Takeshi Yamada

  Pioneering Research Unit for Next Generation, Kyoto University

• Eri Mishima

  Institute for Chemical Research, Kyoto University

• Kazuya Ueki

  Institute for Chemical Research, Kyoto University

• Shigeru Yamago

  Institute for Chemical Research, Kyoto University

抄録

A powerful electrophilic activator for organotellurium compounds was developed. Phenyltellanyl triflate (PhTeOTf) prepared in situ from dibromophenyl(phenyltellanyl)telluride and AgOTf selectively activated various organotellurium compounds in the presence of aromatic compounds yielding the corresponding Friedel–Crafts reaction products. Polymer-end organotellurium compounds were also activated by PhTeOTf providing the corresponding end-functionalized polymers.

収録刊行物

• Chemistry Letters

  Chemistry Letters 37 (6), 650-651, 2008-05-17

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219111169408
• NII論文ID: 10021081497
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2008.650
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/37/6/650/55596428/cl.2008.650.pdf
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