Autoxidation Resistant Cyclopentyl Methyl Ether

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The bond dissociation energy of the C–H bond at the α-position of an ether oxygen in cyclopentyl methyl ether (CPME) has been evaluated theoretically to be 393.3 kJ/mol by using an isodesmic reaction method. Essential factors accounting for this rather higher bond dissociation energy in CPME comparable to secondary C–H bond have been investigated on the basis of the structures and their thermodynamic data such as heats of formation (Δ<I>H</I><SUB>f</SUB><SUP>°</SUP>) of CPME radical and relevant ether radicals evaluated by the theoretical approach.

収録刊行物

  • Chemistry letters

    Chemistry letters 37(7), 774-775, 2008-07-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021082653
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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