Iron Salt-cataltzed Multipoint Alkylation of Pyrrole with Vinyl Ketones

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著者

    • KAWATSURA Motoi
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
    • FUJIWARA Masamune
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
    • UEHARA Hiroyuki
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
    • NOMURA Shun
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
    • HAYASE Shuichi
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
    • ITOH Toshiyuki
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University

抄録

Pyrrole reacted with vinyl ketones in the presence of 3 mol % of iron(II) tetrafluoroborate or alumina-supported iron(III) perchlorate to give multipoint-alkylated products in good yield. Most notably, 4,5-dialkylated 2-acetylpyrrole was obtained in good yield when 2-acetylpyrrole was allowed to react with an excess amount of vinyl ketones.

収録刊行物

  • Chemistry letters

    Chemistry letters 37(7), 794-795, 2008-07-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021082825
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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