J‐PARCで迎える結晶学の新展開  2.J‐PARCがもたらす結晶学の新展開  単結晶中性子回折を用いた結晶相反応の直接観察

書誌事項

タイトル別名
  • Direct Observation of Crystalline-State Reactions by Single Crystal Neutron Diffraction Analyses
  • タンケッショウ チュウセイシ カイセツ オ モチイタ ケッショウソウ ハンノウ ノ チョクセツ カンサツ

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The exchange of some hydrogen atoms with the other hydrogen atoms in the crystallinestate reactions, in which the reaction proceeds with retention of the single crystal form, can be directly observed by single crystal neutron diffraction technique if only the transferred hydrogen atoms were replaced with deuterium atoms before the photoirradiation. The method was successfully applied in the photoisomerization of three kinds of cobalt complex crystals and the mechanism in each reaction has been made clear.

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