Charge Ordered Structure and Dielectric Properties in LuFe2O4
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- MATSUO Yoji
- Osaka Prefecture University, Department of Physical Science
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- YOSHII Kenji
- Japan Atomic Energy Agency
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- IKEDA Naoshi
- Dept. Phys. Okayama Univ.
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- MORI Shigeo
- Osaka Prefecture University
Bibliographic Information
- Other Title
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- 三角格子系鉄複合酸化物LuFe2O4における電荷秩序構造と誘電特性
- サンカク ゴウシケイ テツ フクゴウ サンカブツ LuFe2O4 ニ オケル デンカ チツジョ コウゾウ ト ユウデン トクセイ
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Abstract
Recent works revealed that a ferroelectric polarization in the charge-frustrated system LuFe2O4 originates from an emergence of the charge ordering, which is characterized by a regular arrangement of Fe2+ and Fe3+ ions on the frustrated triangular lattice. In this work, we have investi-gated both the charge ordered (CO) structure and charge ordering processes mainly by means of the transmission electron microscopy (TEM) . Both the CO structure and charge ordering processes depend strongly on the amount of the oxygen deficiency (δ) involved in LuFe2O4-δ. In the case of δ-0, the three-dimensional CO structure with the modulation vector of q= [1/3 1/3 1/2] was formed at room temperature. On the other hand, as δ was increased, the three-dimensional CO structure changed into the two-dimensional CO one and the coherent length becomes shorter along the [001] direction. For proper understanding of the dielectric and magnetic properties in LuFe2O4 and related materials, it should be essential to prepare LuFe2O4-δ samples with properly controlled oxygen-concentration and elucidate the physical properties in LuFe2O4-δ with δ-0.
Journal
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- Nihon Kessho Gakkaishi
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Nihon Kessho Gakkaishi 50 (2), 150-154, 2008
The Crystallographic Society of Japan
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Details 詳細情報について
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- CRID
- 1390282679063377920
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- NII Article ID
- 10021085696
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- NII Book ID
- AN00188364
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- COI
- 1:CAS:528:DC%2BD1cXntVyjs7k%3D
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- ISSN
- 18845576
- 03694585
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- NDL BIB ID
- 9502143
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed