Sulfur isotope ratio of sulfate in rime collected at Mt. Zao, Yamagata Prefecture, Japan

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  • 山形蔵王で採取した着氷に含まれる硫酸イオンの硫黄同位体比
  • ヤマガタ ザオウ デ サイシュシタ チャクヒョウ ニ フクマレル リュウサン イオン ノ イオウ ドウイタイヒ

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Abstract

We collected rime samples on Mt. Zao (near the summit of Mt. Jizo) in two winter seasons (2002-2003 and 2003-2004) and major ionic components and sulfur isotope ratio of sulfate were measured. As a result, almost all the rime samples were obtained under the strong winter climate conditions associated with the flow of the northwestern monsoon from the Asian continent to Mt. Zao. The ∂34S values of non-sea salt sulfate in the rime samples ranged from 4 to 8 ‰ , and almost all the sulfur that originated naturally were transported from the sea. It appears that the formation of sulfur in rime is a result of the mixing of two components (sea water and anthropogenic sulfur). The results obtained indicate the strong possibility of long-range transport from the Asian continent to Mt. Zao through the lower troposphere.

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