New preconcentration technique of Zr, Nb, Mo, Hf, Ta and W employing coprecipitation with Ti compounds : Its application to Lu-Hf system and sequential Pb-Sr-Nd-Sm separation

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著者

    • Makishima Akio MAKISHIMA AKIO
    • The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry (PML), Institute for Study of the Earth's Interior, Okayama University at Misasa
    • Nakamura Eizo NAKAMURA EIZO
    • The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry (PML), Institute for Study of the Earth's Interior, Okayama University at Misasa

抄録

A new preconcentration technique of Zr, Nb, Mo, Hf, Ta and W has been invented employing coprecipiation with Ti compounds. Silicate samples were digested by HF with addition of Ti. Subsequent drying with HClO<sub>4</sub> resulting in complete elimination of fluorine produces Ti compounds (oxide/hydroxides). The sample was then dissolved with dilute nitric acid and centrifuged, and the residual Ti compounds were collected. The Ti compounds forming from 2 mg of Ti without matrix elements concentrate 84-98% of Zr, Nb, Mo, Hf, Ta and W. In 20 mg basaltic and 50 mg peridotitic matrices, the addition of 1 mg of Ti was appropriate and gave yields of 46-69 and 54-79%, respectively, for Zr, Nb, Mo, Hf, Ta and W. Exploiting this preconcentration, sequential separation protocols of Hf, Pb, Sr, Lu, Nd and Sm for isotope analysis are developed with total blanks of 16, 11, 60, 2.4, 3 and 0.4 pg, respectively. The method is suitable for Lu-Hf system studies with capability of simultaneous separation of Pb, Sr, Nd and Sm from the same sample digest as well as isotopic anomaly studies of Zr, Mo and W. As application examples, accurate Lu-Hf data and Pb isotope ratios were obtained for basalt (JB-3) and peridotite (JP-1) by MC-ICP-MS.

収録刊行物

  • Geochemical journal : journal of the Geochemical Society of Japan  

    Geochemical journal : journal of the Geochemical Society of Japan 42(2), 199-206, 2008-04-01 

    GEOCHEMICAL SOCIETY OF JAPAN

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各種コード

  • NII論文ID(NAID)
    10021093378
  • NII書誌ID(NCID)
    AA00654975
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00167002
  • NDL 記事登録ID
    9470253
  • NDL 雑誌分類
    ZM41(科学技術--地球科学)
  • NDL 請求記号
    Z53-R488
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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