Solvent Extraction of Divalent Metal Ions with Azacrown Ether Substituted Acylpyrazolones

• KURAHASHI Kensuke

  Institute for Chemical Research, Kyoto University

• UMETANI Shigeo

  Institute for Chemical Research, Kyoto University

• SOHRIN Yoshiki

  Institute for Chemical Research, Kyoto University

抄録

Novel 4-acyl-5-pyrazolones having aza-15-crown-5 (HPMP-A15C5) and aza-18-crown-6 (HPMP-A18C6) moieties as an intramolecular synergist have been synthesized by simple coupling reactions between 1-phenyl-3-methyl-4-chloroacetyl-5-pyrazolone and the corresponding azacrown ethers. The solvent extraction of the divalent metal ions (Mn²⁺, Co²⁺, Ni²⁺, Cu²⁺, Zn²⁺, Cd²⁺ and Pb²⁺) were examined. Synergistic extractions with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (HPMBP) and benzocrown ethers were also examined for a comparison. Extractions with the novel acylpyrazolones were unique and quite different from those with HPMBP and benzocrown ethers. The synergistic effect with benzocrown ethers was low, and an obvious difference brought by the ring size was not observed. The extractions of the divalent metal ions with HPMP-A18C6 were generally enhanced, as compared to those alone with HPMBP; on the contrary, the extractions with HPMP-A15C5 were relatively poor.

収録刊行物

• Analytical Sciences

  Analytical Sciences 24 (2), 225-229, 2008

  社団法人 日本分析化学会

キーワード

• Analytical Chemistry

詳細情報

• CRID: 1390282679235151232
• NII論文ID: 130004441605
• NII論文ID: 10021098408
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.24.225
• ISSN: 13482246
• ISSN: 09106340
• NDL書誌ID: 9362844
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9362844
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.24.225.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.24.225/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/24/2/24_2_225/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可