Vinylferrocene Homopolymer and Copolymers : An Electrochemical Comparison

この論文にアクセスする

この論文をさがす

著者

抄録

Poly(vinylferrocene) (pVFc) homopolymer was synthesized by free radical polymerization, along with a series of pVFc-based copolymers containing either styrene, vinylanthracene or methylmethacrylate. This report details the electrochemical experiments conducted to examine the stability of the various pVFc based polymers, which is shown to be critically dependent on the extent of copolymerization. A trend was found that when the concentration of co-monomer was decreased, electrochemical stability was enhanced. Furthermore incorporation of a second monomer into the polymer chain produced a profound effect on the scan rate behaviour of the vinylferrocene moiety. As the concentration of co-monomer was decreased, the behaviour tended towards that of a diffusion controlled process. These results are of vital significance for the development of pVFc-based electrochemical sensors.

収録刊行物

  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

    Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 24(3), 339-343, 2008-03-10

    The Japan Society for Analytical Chemistry

参考文献:  34件中 1-34件 を表示

  • <no title>

    SULAK M. T.

    Biosens. Bioelectron. 21, 1719, 2006

    被引用文献1件

  • <no title>

    SLJUKIC B.

    Analyst 131, 670, 2006

    被引用文献1件

  • <no title>

    GULCE H.

    Enzyme Microb. Technol. 32, 895, 2003

    被引用文献1件

  • <no title>

    GOKDOGAN O.

    Chem. Eng. J. 116, 39, 2006

    被引用文献1件

  • <no title>

    ROBINSON K. L.

    Electrochem. Commun. 8, 1055, 2006

    被引用文献1件

  • <no title>

    KAVANOZ M.

    Turkish J. Chem. 28, 287, 2004

    被引用文献1件

  • <no title>

    ROBINSON K. L.

    Electroanalysis 18, 677, 2006

    被引用文献1件

  • <no title>

    ROBINSON K. L.

    Anal. Chem. 78, 2450, 2006

    被引用文献1件

  • <no title>

    HICKMAN J. J.

    Science 252, 688, 1991

    被引用文献3件

  • <no title>

    PATEL H.

    Biosens. Bioelectron. 18, 1073, 2003

    被引用文献1件

  • <no title>

    GUNDOGAN-PAUL M.

    Biosens. Bioelectron. 17, 875, 2002

    被引用文献2件

  • <no title>

    HILLMAN A. R.

    Langmuir 7, 191, 1991

    被引用文献1件

  • <no title>

    LEDDY J.

    J. Electroanal. Chem. 189, 203, 1985

    被引用文献1件

  • <no title>

    PEERCE P. J.

    J. Electroanal. Chem. 112, 97, 1980

    被引用文献1件

  • <no title>

    PEERCE P. J.

    J. Electronal. Chem. 114, 89, 1980

    被引用文献3件

  • <no title>

    MERZ A.

    J. Am. Chem. Soc. 100, 3222, 1978

    被引用文献2件

  • <no title>

    HILLMAN A. R.

    J. Chem. Soc. Faraday Trans. 87, 2047, 1991

    被引用文献1件

  • <no title>

    UMANA M.

    Anal. Chem. 53, 1170, 1981

    被引用文献1件

  • <no title>

    DAUTARTAS M. F.

    J. Electroanal. Chem. 109, 301, 1980

    被引用文献2件

  • <no title>

    INZELT G.

    Electrochim. Acta 31, 1381, 1986

    被引用文献1件

  • <no title>

    CHAMBERS J. Q.

    Anal. Chem. 57, 1117, 1985

    被引用文献1件

  • Tetracyanoquinodimethane-modified electrodes

    DAY R. W.

    J. Am. Chem. Soc. 104, 6804-6805, 1982

    被引用文献2件

  • <no title>

    GLIDLE A.

    Langmuir 19, 7746, 2003

    被引用文献1件

  • <no title>

    BRUCKENSTEIN S.

    J. Electrochem. Soc. 150, E285, 2003

    被引用文献1件

  • <no title>

    JUREVICIUTE I.

    J. Electroanal. Chem. 488, 73, 2000

    被引用文献1件

  • <no title>

    BRUCKENSTEIN S.

    J. Phys. Chem. B 102, 4994, 1998

    被引用文献1件

  • <no title>

    BRUCKENSTEIN S.

    J. Electrochem. Soc. 145, L24, 1998

    被引用文献1件

  • <no title>

    HILLMAN A. R.

    J. Electrochem. Soc. 139, 74, 1992

    被引用文献1件

  • <no title>

    BARBERO C.

    Electrochim. Acta 45, 3895, 2000

    被引用文献1件

  • <no title>

    INZELT G.

    Electrochim. Acta 37, 647, 1992

    被引用文献1件

  • <no title>

    AMATORE C.

    Chem. Eur. J. 7, 2206, 2001

    被引用文献2件

  • <no title>

    AMATORE C.

    Chem. Phys. Chem. 2, 130, 2001

    被引用文献1件

  • <no title>

    BAKER M. V.

    Aust. J. Chem. 57, 207, 2004

    被引用文献1件

各種コード

  • NII論文ID(NAID)
    10021098892
  • NII書誌ID(NCID)
    AA10500785
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    09106340
  • NDL 記事登録ID
    9417295
  • NDL 雑誌分類
    ZP4(科学技術--化学・化学工業--分析化学)
  • NDL 請求記号
    Z54-F482
  • データ提供元
    CJP書誌  NDL  J-STAGE 
ページトップへ