Mossbauer Spectroscopy : Nuclear Hyperfine Technique for Studying Dynamic Chemical States of Iron Complexes

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著者

    • MAEDA Y.
    • Department of Chemistry, Faculty of Sciences, Kyushu University

抄録

Mössbauer effect spectroscopy is one of the most important techniques for observing the dynamic phenomena of electronic states in solid. The Mössbauer spectra of mixed valence compounds show relaxation spectra if the electronic states are changed dynamically between Fe<SUP>2+</SUP> and Fe<SUP>3+</SUP>. The dynamic electronic states of mixed valence compounds are discussed in connection with Mössbauer spectra of [Fe<SUB>2</SUB> (bpmp) (ppa) <SUB>2</SUB>]X<SUB>2</SUB> as examples. The absorption spectra and cyclic voltammograms of the compounds were measured. The electronic states of the mixed compounds are dependent on the species of their anions in the solid state.

収録刊行物

  • Journal of Nuclear and Radiochemical Sciences  

    Journal of Nuclear and Radiochemical Sciences 7(1), R13-R18, 2006-06-01 

    The Japan Society of Nuclear and Radiochemical Sciences

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各種コード

  • NII論文ID(NAID)
    10021101016
  • NII書誌ID(NCID)
    AA11948402
  • 本文言語コード
    ENG
  • 資料種別
    REV
  • ISSN
    13454749
  • データ提供元
    CJP書誌  J-STAGE 
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