^<57>Fe Mossbauer Parameters of Two Crystal Polymorphs of Fc^+AsF_6^- and the Sign of the Quadrupole Splitting in the Ferrocenium Ion

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Temperature-dependent <SUP>57</SUP>Fe Mössbauer effect spectroscopy has been used to characterize the hyperfine and dynamical properties of the metal atom in two crystallographic forms of ferrocenium hexafluoroarsenate. The temperature dependence of the recoil-free fraction and the spin-lattice relaxation rates have been determined over the interval 89<T<300 K and shows a small difference between the two crystallographic forms. The sign of the quadrupole splitting parameter in the Fc<SUP>+</SUP> cation has been elucidated in a transverse magnetic field experiment at room temperature.

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  • Journal of Nuclear and Radiochemical Sciences

    Journal of Nuclear and Radiochemical Sciences 7(1), 13-15, 2006-06-01

    The Japan Society of Nuclear and Radiochemical Sciences

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各種コード

  • NII論文ID(NAID)
    10021101325
  • NII書誌ID(NCID)
    AA11948402
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    13454749
  • データ提供元
    CJP書誌  J-STAGE 
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