Development of a Geometrical Model for Optimizing Porous Anode Microstructure of Solid Oxide Fuel Cells
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- Mori Hidetoshi
- Department of Robot Systems Engineering, Aichi University of Technology
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- Nonaka Noboru
- Department of Robot Systems Engineering, Aichi University of Technology
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- Mizuno Mitsukuni
- Department of Mechanical Engineering, Aichi Institute of Technology
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- Abe Hiroya
- Joining and Welding Research Institute, Osaka University
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- Naito Makio
- Joining and Welding Research Institute, Osaka University
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A geometrical model has been developed to optimize the microstructure of porous composite anode electrodes of solid oxide fuel cells. The model takes into account the coordination number theory applied to a random packing of binary particle mixture, together with the percolation theory introduced to provide percolation paths for electrons and ions. The predictions confirm that the effective triple-phase-boundary (TPB) index deduced from a geometric analysis depends on the pore size as well as the characteristic parameters including particle radius ratio, contact angle and composition ratio. The influence of pore size on the effective TPB index is particularly conspicuous, suggesting that the pore size optimization should improve the effective TPB index significantly.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 41 (4), 246-253, 2008
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204568509824
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- NII論文ID
- 10021109988
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- NII書誌ID
- AA00709658
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- COI
- 1:CAS:528:DC%2BD1cXmvVaht7k%3D
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 9462795
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 使用不可