Topological Polymer Chemistry

  • TEZUKA Yasuyuki
    Dept. of Organic and Polymeric Materials, Tokyo Institute of Technology

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Other Title
  • 数学と高分子  高分子トポロジー化学―ポアンカレと視る高分子の「かたち」―
  • コウブンシ トポロジー カガク ポアンカレ ト ミル コウブンシ ノ カタチ
  • ポアンカレと視る高分子の「かたち」

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Abstract

Basic principles and recent progress of topological polymer chemistry is outlined. A systematic classification of nonlinear polymer topologies is discussed based on constitutional isomers of alkanes and cycloalkanes. Topological isomerism occurs specifically on randomly coiled, flexible polymer molecules having cyclic and linear structures. An “electrostatic self-assembly and covalent fixation” strategy has been developed to design topologically unique nonlinear polymer constructions.

Journal

  • Kobunshi

    Kobunshi 57 (2), 81-85, 2008

    The Society of Polymer Science, Japan

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