有機合成化学と高分子科学　　遷移金属錯体触媒を用いる芳香族ポリマーの精密合成

• 東村 秀之

  住友化学(株)

書誌事項

タイトル別名

• Precision Synthesis of Aromatic Polymers by Transition Metal Complex Catalysts
• センイ キンゾク サクタイ ショクバイ オ モチイル ホウコウゾク ポリマー ノ セイミツ ゴウセイ

抄録

Precision synthesis of aromatic polymers by transition metal catalysts has greatly progressed. Oxidative polymerization of phenolic monomers has been recently reconsidered as a clean synthetic method. The regioselectivity for the polymerization of 2and/or 6-unsubstituted phenols can be controlled by a radical-controlled catalyst, a catalyst immobilized on mesoporous materials, and so on. The asymmetric oxidative coupling polymerization of naphthol derivatives by a chiral catalyst is also found. The C-C cross coupling such as Kumada-Tamao type and Suzuki-Miyaura type has been actively applied to a polymerization method. Not only the head-to-tail selectivity is regulated, but also molecular weight distribution is controlled via catalyst transfer polycondensation.

収録刊行物

• 高分子

  高分子 57 (3), 138-141, 2008

  公益社団法人 高分子学会

キーワード

• Aromatic Polymer
• Transition Metal Catalyst
• Radical-Controlled Oxidative Polymerization
• Asymmetric Oxidative Coupling Polymerization
• Catalyst Transfer Polycondensation

詳細情報

• CRID: 1390001204080248960
• NII論文ID: 10021119031
• NII書誌ID: AN00084926
• DOI: 10.1295/kobunshi.57.138
• COI: 1:CAS:528:DC%2BD1cXksl2isLc%3D
• ISSN: 21859825
• ISSN: 04541138
• NDL書誌ID: 9400817
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9400817
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可