Synthesis and Chemical Recycling of Polyurethane Materials Containing Acetal Linkages

  • HASHIMOTO Tamotsu
    Dep. of Materials Science and Engineering, Graduate School of Engineering, University of Fukui

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Other Title
  • 高分子のケミカルリサイクル  アセタール結合を有するポリウレタンフォームの合成とそのケミカルリサイクル
  • アセタール ケツゴウ オ ユウスル ポリウレタン フォーム ノ ゴウセイ ト ソノ ケミカル リサイクル

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Abstract

This review concerns development of new chemically recyclable polyurethanes foams and elastomers. The key strategy is the introduction of acetal linkages into polyurethane backbones using acetal-containing polyols as raw materials. A treatment of these polyurethanes with aqueous acid at room temperature caused smooth hydrolysis reaction of the acetal linkages to produce polyols in high yield and high purity as degradation products.

Journal

  • Kobunshi

    Kobunshi 57 (5), 350-353, 2008

    The Society of Polymer Science, Japan

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