合金めっきの立場から見た亜鉛電解採取における不純物効果 Impurity Effect in Zinc Electrowinning Viewed from a Standpoint of Alloy Plating

この論文にアクセスする

この論文をさがす

著者

抄録

Bath composition and operating conditions were compared between the electrowinning in hydrometallurgical production of Zn and the electroplating of single Zn and Zn alloys with iron-group metals in the production of corrosion resistant steel sheets. Both electrochemical processes were equivalent in a sense that Zn deposition proceeded on the metal cathode using insoluble anode from the sulfate baths where Zn existed in its simplest form of hydrated ion although the acidity of the bath was greatly different from each other. The electrochemical meaning of the critical current density, at which Zn began to deposit, was clarified first on the basis of the requirement permitting the deposition of less noble Zn in the presence of more noble hydrogen ions in the bath. Then the codeposition behavior of secondary element, <I>i.e.</I> an impurity in electrowinning and an alloying constituent in alloy plating, was explained by the theory of regular and anomalous type alloy deposition. According to its electrochemical meaning, the effect of secondary element in the bath on the magnitude of the critical current density was predicted, which agreed well with the experimental results. Further, the dissolution behavior of deposited Zn was discussed in relation to the mechanism in which the critical current density was changed in the presence of impurity in Zn electrowinning bath.

収録刊行物

  • Journal of MMIJ : journal of the Mining and Materials Processing Institute of Japan

    Journal of MMIJ : journal of the Mining and Materials Processing Institute of Japan 124(3), 159-165, 2008-03-25

    The Mining and Materials Processing Institute of Japan

参考文献:  24件中 1-24件 を表示

  • <no title>

    MANTELL C. L.

    Electrochemical Engineering, 1960

    被引用文献1件

  • <no title>

    ISHII K.

    An Introduction to Iron and Steel Processing, 2006

    被引用文献1件

  • <no title>

    HITETSU KINZOKUSEIREN 2, 224-226, 1980

    被引用文献1件

  • <no title>

    FUKUSHIMA H.

    J. Metal Finishing Soc. Japan 33, 574-578, 1982

    被引用文献1件

  • <no title>

    SAKATA M.

    Proc. Int. Symposium on Lead and Zinc Processing, (Kyoto, 2005), 2005

    被引用文献1件

  • <no title>

    TAKAHASHI M.

    KOGYOUDENKAINOKAGAKU, 1979

    被引用文献1件

  • <no title>

    KINZOKU BINRAN

    Japan Inst. Metals, 2003

    被引用文献1件

  • <no title>

    TOSHIMA S.

    KISO DENKIKAGAKU, 1965

    被引用文献1件

  • <no title>

    HINO T.

    Proc. 48^<th> Meeting of 69 Committee, JSPS, (Tokyo, 2007), 2007

    被引用文献1件

  • <no title>

    OKI T.

    KINZOKUDENKIKAGAKU, 1969

    被引用文献1件

  • <no title>

    OHGAI T.

    Proc. Int. Symposium on Extraction and Application of Zinc and Lead, (Sendai, 1995), 1995

    被引用文献1件

  • <no title>

    FUKUSHIMA H.

    Journal of MMIJ 109, 861-964, 1993

    被引用文献1件

  • <no title>

    FUKUSHIMA H.

    Journal of MMIJ 110, 967-972, 1994

    被引用文献1件

  • <no title>

    FUKUSHIMA H.

    KINZOKU 75, 1125-1130, 2005

    被引用文献1件

  • <no title>

    FUKUSHIMA H.

    J. Surface Finishing Soc. Japan 41, 888-893, 1990

    被引用文献1件

  • <no title>

    TANABE K.

    Proc. Int. Symposium on Extraction and Application of Zinc and Lead, (Sendai, 1995), 1995

    被引用文献1件

  • <no title>

    AKIYAMA T.

    J. Metal Finishing Soc. Japan 37, 20-24, 1986

    被引用文献1件

  • <no title>

    LEE R.

    J. Metal Finishing Soc. Japan 37, 660-664, 1986

    被引用文献1件

  • <no title>

    BOCKRIS J. O'M.

    J. Electrochem. Soc. 108, 676-685, 1961

    被引用文献1件

  • <no title>

    NAKANO H.

    Journal of MMIJ 120, 39-42, 2004

    被引用文献1件

  • <no title>

    FUKUSHIMA H.

    Metall 42, 242, 1988

    被引用文献3件

  • <no title>

    FUKUSHIMA H.

    Metall Vol. 44, 754-759, 1990

    被引用文献2件

  • Mechanism of Anomalous Type Electrodeposition of Fe-Ni Alloys from Sulfate Solutions

    Nakano Hiroaki , Matsuno Masayuki , Oue Satoshi , YANO Masaaki , KOBAYASHI Shigeo , FUKUSHIMA Hisaaki

    Materials transactions 45(11), 3130-3135, 2004-11-20

    参考文献19件 被引用文献1件

  • 亜鉛電解採取における電析亜鉛の再溶解

    大貝 猛 , 福島 久哲 , 秋山 徹也 , 平井 豊

    資源と素材 : 資源・素材学会誌 : journal of the Mining and Materials Processing Institute of Japan 112(12), 885-891, 1996-08-10

    参考文献15件 被引用文献3件

被引用文献:  1件中 1-1件 を表示

各種コード

  • NII論文ID(NAID)
    10021121338
  • NII書誌ID(NCID)
    AA12188381
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    18816118
  • NDL 記事登録ID
    9440765
  • NDL 雑誌分類
    ZP41(科学技術--金属工学・鉱山工学)
  • NDL 請求記号
    Z17-315
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
ページトップへ