Synthesis conditions of graphite intercalation compound with Ca in molten Li-Ca alloy and its superconducting characteristics
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- Toyoda Masahiro
- Oita University
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- Takenaka Asami
- Oita University
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- Takano Yoshihiko
- National Institute for Materials Science
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- Akuzawa Noboru
- Tokyo National College of Technology
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- Yoshida Akira
- Musashi Institute of Technology
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- Kaburagi Yutaka
- Musashi Institute of Technology
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Abstract
Binary intercalation compound CaC6 was synthesized by soaking the platelet of HOPG into the molten Li-Ca alloy (Li/Ca=4.0) at 350°C for a long soaking (more than 10 days). The C ompound CaC6 thus synthesized was confirmed to be superconductive with the critical temperature of about 10 K. For the synthesis of the superconductive intercalation compound CaC6, the crystallinity of the host graphite has to be selected and long soaking in molten Li-Ca alloy is also required. Superconductivity of CaC6 was supposed to belong in second type.
Journal
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- TANSO
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TANSO 2008 (233), 148-150, 2008
THE CARBON SOCIETY OF JAPAN
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Details 詳細情報について
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- CRID
- 1390001204226193280
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- NII Article ID
- 130004358747
- 10021127834
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- NII Book ID
- AN00140335
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- ISSN
- 18845495
- 03715345
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- NDL BIB ID
- 9549980
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed