Thermoelectric Properties of Sr-Ru-O Compounds Prepared by Spark Plasma Sintering
-
- Keawprak Nittaya
- Institute for Materials Research, Tohoku University
-
- Tu Rong
- Institute for Materials Research, Tohoku University
-
- Goto Takashi
- Institute for Materials Research, Tohoku University
この論文をさがす
抄録
Sr-Ru-O in the ratio of Ru to Sr (RRu/Sr) from 0.5 to 1.2 were prepared by spark plasma sintering (SPS) and the effect of composition on the electrical conductivity (σ), thermal conductivity (κ) and Seebeck coefficient (S) was investigated. All compositions yielded dense sintered mass with around 90–100% of a theoretical density. SrRuO3 and Sr2RuO4 in a single phase were obtained at RRu/Sr=1.0 and 0.5, respectively. The second phases were identified, i.e., RuO2 and Ru at RRu/Sr>1.0 and Sr3Ru2O7 and Sr2RuO4 at RRu/Sr<1.0. The σ increased with increasing RRu/Sr in the RRu/Sr range from 0.8 to 1.2 at room temperature exhibiting a metallic behavior, whereas the σ showed a semiconducting behavior at RRu/Sr=0.5. The κ was around 2 to 7 Wm−1 K−1 at RRu/Sr=0.8 to 1.2 at room temperature and slightly increased with increasing temperature and RRu/Sr. The κ decreased with increasing temperature at RRu/Sr=0.5. The S was around 25–40 μV K−1 at room temperature, almost independent of compositions. The S slightly decreased with temperature at RRu/Sr=0.8 to 1.0, whereas the S increased with temperature and showed a maximum around 500 to 600 K at RRu/Sr=1.2. The S significantly decreased with increasing temperature at RRu/Sr=0.5. The highest dimensionless figure of merit (ZT) was 0.06 at RRu/Sr=1.2 at 600 K.
収録刊行物
-
- MATERIALS TRANSACTIONS
-
MATERIALS TRANSACTIONS 49 (3), 600-604, 2008
公益社団法人 日本金属学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390001204249699200
-
- NII論文ID
- 10021145183
- 130004453948
-
- NII書誌ID
- AA1151294X
-
- ISSN
- 13475320
- 13459678
-
- HANDLE
- 10097/52385
-
- NDL書誌ID
- 9413208
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- IRDB
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可