Surface Protection Effect of Diffusion Pack Cementation Process by Al-Si Powders with Chloride Activator on Magnesium and Its Alloys

  • Park Joon Sik
    Advanced Materials Engineering, Hanbat National University
  • Kim Jeong Min
    Advanced Materials Engineering, Hanbat National University
  • Kim Ha Young
    Advanced Materials Engineering, Hanbat National University
  • Lee Jae Seol
    Materials and Parts team, Korea Institute of Industrial Technology
  • Oh Ik Hyun
    Materials and Parts team, Korea Institute of Industrial Technology
  • Kang Chang Suck
    Materials and Parts team, Korea Institute of Industrial Technology

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Diffusion pack coatings via Al-Si powders with an AlCl3 chloride activator have been investigated in order to examine the surface protection effect on pure magnesium and magnesium alloys. Pure Magnesium and commercial AZ31 magnesium alloys have been subjected to diffusion coatings in an Al alloy powder for various time frames. When the pack coating was carried out at 823 K for 15 h, the Mg17Al12 layer has been successfully synthesized on the pure magnesium substrate. Similarly, a pack annealing at 823 K for 15 h showed a synthesized Mg-Al layer on the AZ31 magnesium alloy as a coating layer. Mechanisms for the surface layer formation are discussed together with growth kinetics and microstructural observations.

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