Phase Equilibria and Microstructure on γ′ Phase in Co-Ni-Al-W System

  • Shinagawa Kazuya
    Department of Materials Science, Graduate School of Engineering, Tohoku University
  • Omori Toshihiro
    Department of Materials Science, Graduate School of Engineering, Tohoku University
  • Sato Jun
    Department of Materials Science, Graduate School of Engineering, Tohoku University
  • Oikawa Katsunari
    Department of Materials Science, Graduate School of Engineering, Tohoku University
  • Ohnuma Ikuo
    Department of Materials Science, Graduate School of Engineering, Tohoku University
  • Kainuma Ryosuke
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
  • Ishida Kiyohito
    Department of Materials Science, Graduate School of Engineering, Tohoku University

Bibliographic Information

Other Title
  • Phase Equilibria and Microstructure on γ' Phase in Co-Ni-Al-W System
  • Phase equilibria and microstructure on g phase in Co Ni al W system
  • Phase Equilibria and Microstructure on γ′ Phase in Co-Ni-Al-W System

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Abstract

Phase equilibria between the γ and γ′ phases at 900°C in the Co-(10–70)Ni-Al-W system were determined by electron probe microanalysis (EPMA) and X-ray diffractometry (XRD). It was found that the γ′ phase with L12 structure continuously exists from the Co side to the Ni side in Co-Ni-Al-W system and that it widens to the low W region with increasing Ni content. The partition of Al into the γ′ phase increased with Ni content, while the W changed from a γ′ former to a γ former by increase of Ni content. Differential scanning calorimetry (DSC) measurements also revealed that the γ′ solvus temperature increases with Ni content, while the solidus temperature is hardly affected by such content. The lattice parameter of the γ and γ′ phases and the mismatch decreased with increasing Ni content, which caused the morphologic change of the γ′ precipitates from cubes to spheres.

Journal

  • MATERIALS TRANSACTIONS

    MATERIALS TRANSACTIONS 49 (6), 1474-1479, 2008

    The Japan Institute of Metals and Materials

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