Physical Properties of Deposits Obtaining from Boric Acid Free Sulfamate Ni Bath
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- NAKAMARU Yaichirou
- Graduate School of Engineering, Kanto Gakuin University Kanto Gakuin University Surface Engineering Research Institute
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- WAKUDA Yohei
- Graduate School of Engineering, Kanto Gakuin University Kanto Gakuin University Surface Engineering Research Institute
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- TASHIRO Katsuhiko
- Kanto Gakuin University Surface Engineering Research Institute
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- WATANABE Mitsuhiro
- Kanto Gakuin University Surface Engineering Research Institute
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- HONMA Hideo
- Kanto Gakuin University Surface Engineering Research Institute Faculty of Engineering, Kanto Gakuin University
Bibliographic Information
- Other Title
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- ホウ酸代替物質を使用したスルファミン酸ニッケル浴から得られためっき皮膜物性とその応用
- ホウサン ダイタイ ブッシツ オ シヨウシタ スルファミンサン ニッケルヨク カラ エラレタ メッキ ヒマク ブッセイ ト ソノ オウヨウ
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Abstract
Boric acid has been an essential substance in plating technology for obtaining good film properties and for improving bath life. However, there are restrict ions against Boron in waste water ; therefore the development of a boric acid free nickel electroplating bath was in demanded.</br>In our previous paper, we attempted to develop a boric acid-free sulfamate Ni plating bath. We examined over 20 kinds of plating solutions with alternative chemicals, and found that acetic acid, propionic acid, Ni acetate, and citric acid were recognized as potential candidates to obtain similar film properties and appearance. This paper reports the evaluation of deposited film properties obtained using these four kinds of organic acid baths. Acetic acid, propionic acid, and Ni acetate, as replacements for boric acid, exhibited similar properties as those obtained by boric acid. The propionic acid bath showed less pit defects even after thick film formation without surfactants. Accordingly, it appears to be a favorable boric acid replacement for those applications that require thicker require films.
Journal
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- Journal of The Surface Finishing Society of Japan
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Journal of The Surface Finishing Society of Japan 59 (2), 133-137, 2008
The Surface Finishing Society of Japan
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Details 詳細情報について
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- CRID
- 1390001204118935552
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- NII Article ID
- 10021169436
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- NII Book ID
- AN1005202X
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- COI
- 1:CAS:528:DC%2BD1cXjtFyht7s%3D
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- ISSN
- 18843409
- 09151869
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- NDL BIB ID
- 9370767
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed