一酸化炭素あるいは水素の脱離を推進力とする炭素-炭素結合生成反応およびその関連反応 Carbon-carbon Bond Formation Reaction Promoted by Elimination of Carbon Monoxide or Hydrogen and the Related Reactions

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著者

    • 米澤 宣行 YONEZAWA Noriyuki
    • 東京農工大学工学部有機材料化学科 Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology

抄録

The acid mediated carbon-carbon bond formation promoted by elimination of small molecule of carbon monoxide or hydrogen and the related reactions are discussed. The specific decarbonyla-tive arylation reactions of a-alkoxy- or a-oxocarboxylic acids with the aid of acidic mediator such as P<sup>2</sup>O<sup>5</sup>-MSOH or TFOH affording various arylated products are presented. Furthermore, the acid mediated dehydrogenafive formation of enol ethers or equivalents followed by crossed-aldol addition to activated benzaldehyde derivative or equivalents giving a, β-unsaturated carbonyl compounds or 1-alkoxy-2-alkylindenes is discussed. The elucidation of the structural requirements, the reaction routes, and the reaction mechanisms for these molecular transformations are described in detail. Some related reaction behaviors such as distinction in regiospecificity and dependence on acidic mediator of acid-mediated aroylation of γ- or δ-oxocarboxylic acids and intramolecular electrophilic aromatic substitution of a-alkylcinnamaldehydes affording 1-alkoxy-2-alkylindenes are also discussed.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN  

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 66(2), 158-171, 2008-02-01 

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10021173775
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    9379058
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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