カルボニル化合物の触媒的不斉アルキニル化反応の新展開 [in Japanese] New Development in Catalytic Asymmetric Alkynylation of Carbonyl Compounds [in Japanese]
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The enantionselective addition of terminal acetylenes to aldehydes or ketones affords a direct access to optically active propargyl alcohols which are useful, versatile synthetic intermediates. This mini review focuses on the recent advances in zinc (II) and indium (III) salts-mediated asymmetric alkynylation on carbonyl compounds via in situ "catalytic" generation of metal acetylide.
- J. Synth. Org. Chem. Jpn.
J. Synth. Org. Chem. Jpn. 66(2), 172-173, 2008-02-01
The Society of Synthetic Organic Chemistry, Japan