New Development in Catalytic Asymmetric Alkynylation of Carbonyl Compounds

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Other Title
  • カルボニル化合物の触媒的不斉アルキニル化反応の新展開

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Abstract

The enantionselective addition of terminal acetylenes to aldehydes or ketones affords a direct access to optically active propargyl alcohols which are useful, versatile synthetic intermediates. This mini review focuses on the recent advances in zinc (II) and indium (III) salts-mediated asymmetric alkynylation on carbonyl compounds via in situ "catalytic" generation of metal acetylide.

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Details 詳細情報について

  • CRID
    1390001205312844032
  • NII Article ID
    10021173826
  • NII Book ID
    AN0024521X
  • DOI
    10.5059/yukigoseikyokaishi.66.172
  • ISSN
    18836526
    00379980
  • Text Lang
    ja
  • Data Source
    • JaLC
    • Crossref
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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