9族金属錯体の水素移動触媒機能を活用する効率的有機合成反応の開発 Group 9 Metal Complex-catalyzed Hydrogen Transfer Reactions and Their Application to Organic Synthesis

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著者

    • 藤田 健一 FUJITA Ken-ichi
    • 京都大学大学院地球環境学堂, 京都大学大学院人間・環境学研究科 Graduate School of Global Environmental Studies, and Graduate School of Human and Environmental Studies, Kyoto University

抄録

Development of methodology directed toward environmentally benign molecular transformations is one of the most important subjects in modern synthetic organic chemistry. As a promising method for environmentally benign transformation of organic molecules, we have focused on the transition metal catalyzed "Hydrogen Transfer Reactions". Here, we report our recent studies on hydrogen transfer reactions catalyzed by group 9 metal complexes bearing Cp*(η5-pentamethyl-cyclopentadienyl) ligand and their application to organic synthesis, which include (1) Cp*Ir complex-catalyzed oxidation of alcohols, (2) Cp Ir complex-catalyzed transfer hydrogenation of nitrogen heteroaromatics using 2-propanol as a hydrogen donor, (3) Cp Ir complex-catalyzed carbon-nitrogen and carbon-carbon bond formation using alcohols as alkylating reagents, (4) Cp Ir and Cp Rh complex-catalyzed synthesis of nitrogen heterocycles by intra- and intermolecular carbon-nitrogen bond formation.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN  

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 66(4), 322-331, 2008-04-01 

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10021174381
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    9459924
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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