主鎖型反応性有機金属ポリマーの設計とこれを経由する多彩なπ共役高分子の創製 Creation of Diverse π-Conjugated Polymers via Main Chain-reactive Organometallic Polymers

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著者

    • 冨田 育義 TOMITA Ikuyoshi
    • 東京工業大学大学院総合理工学研究科 Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology

抄録

Polymers possessing reactive organometallic repeating units in the main chain are potentially applicable to novel reactive polymers which serve as powerful synthetic precursors for various main chain-functionalized materials. Accordingly, organometallic polymers containing metallacycles such as cobaltacyclopentadiene and titanacyclopentadiene were prepared and their reactions were studied. The metallacyclopentadiene-containing polymers were prepared by the reactions of diynes with low-valent organometallic complexes. Cobaltacyclopentadiene-containing polymers are air-stable materials that can be converted into other organocobalt polymers possessing cyclobutadinecobalt and cobalticinium units and into organic polymers with diverse main chain functionality. Likewise, regioregular organotitanium polymers produced from aromatic terminal diynes and low-valent titanium complexes provide ic-conjugated organic polymers possessing unsaturated backbones in the main chain by their polymer reactions. Properties of the organometallic polymers will also be described.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN  

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 66(5), 436-443, 2008-05-01 

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10021174901
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    9503878
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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