高感度光重合開始系の最近の進歩 Recent Progress of Highly Sensitive Photo-Polymerization Initiation

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著者

    • 青合 利明 AOAI Toshiaki
    • 富士フイルム株式会社R&D統括本部 有機合成化学研究所 Synthetic Organic Chemistry Laboratories, Research & Development Management Headquarters, FUJIFILM Corporation

抄録

A photopolymer material has been widely used in negative-type photosensitive composition (e.g. as a radical or an acid catalyzed polymerization). A large number of photo-initiator com-pounds for these compositions have been developed corresponding to many industrial demands such as coatings (overcoats, adhesives), graphic materials (printing plates, inks), electronic materi-als (printed circuit, micro-resist, color filter), and recording materials (holography). With recent development of light source especially for IR, Visible, and UV lasers, there is a growing interest to increase their photo-sensitivity. To perform much higher sensitivity, dye sensitizers are usually utilized in both radical and cationic photo-polymerization, and are elaborately designed in combi-nation of initiators. The dye sensitization is mainly classified into 1) electron transfer mechanism and 2) energy transfer mechanism. The dyes, therefore, are controlled and adjusted to their physi-cal properties such as wave length, redox potential, and excited energy level according to the mechanism. In this paper, the classification of these initiators/dye sensitizers and their character-istics are shortly described. Furthermore a few recent applications are introduced as an example of high sensitive material.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN  

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 66(5), 458-467, 2008-05-01 

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10021175007
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    00379980
  • NDL 記事登録ID
    9503955
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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