高性能有機トランジスタに向けた有機半導体の分子設計 Molecular Design of Organic Semiconductors for High Performance Organic Field-effect Transistors

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著者

    • 西田 純一 NISHIDA Jun-ichi
    • 東京工業大学大学院総合理工学研究科 Interdisciplinary Graduate School of Sci. and Eng., Tokyo Institute of Technology
    • 山下 敬郎 YAMASHITA Yoshiro
    • 東京工業大学大学院総合理工学研究科 Interdisciplinary Graduate School of Sci. and Eng., Tokyo Institute of Technology

抄録

Much attention has been focused on organic field-effect transistors (OFET) s from view point of application purposes for electronic devices as well as basic interest in charge transportation. Development of new semiconductors showing high-performance FET characteristics is particularly important to make progress in this field. For this purpose, we have designed various kinds of heterocyclic compounds with electron-donating or accepting properties. We have used tetrathiafulvalene (TTF) derivatives as semiconductors. High hole mobilities were achived by introducing naphthalene (0.42 cm2/Vs) or quinoxaline (0.20 cm2/Vs) rings to the TTF unit. Furthermore, we have introduced electron-withdrawing halogen groups into the quinoxaline group and found that the derivatives showed high performance n-type behavior. We have also developed high performance n-type FETs by introducing trifluoromethylphenyl groups in heterocyclic π-electron systems. The bithiazole and thiazolothiazole derivatives showed high electron mobilites over 1 cm2/Vs. Decrease of the threshold values was accomplished by introducing strong electron-withdrawing heterocycles such as a benzothiadiazole ring.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 66(5), 515-524, 2008-05-01

    The Society of Synthetic Organic Chemistry, Japan

参考文献:  44件中 1-44件 を表示

  • <no title>

    NEWMAN C. R.

    Chem. Mater. 16, 4436, 2004

    被引用文献1件

  • <no title>

    TAKATA M.

    Jpn. J. Appl. Phys. 41, L4, 2002

    被引用文献1件

  • <no title>

    MORIOKA Y.

    Chem. Lett. 33, 1632, 2004

    被引用文献1件

  • <no title>

    MAS-TORRENT M.

    J. Am. Chem. Soc. 126, 984, 2004

    被引用文献1件

  • <no title>

    MAS-TORRENT M.

    Appl. Phys. Lett. 86, 012110, 2005

    被引用文献1件

  • <no title>

    NODA B.

    Chem. Lett. 34, 392, 2005

    被引用文献1件

  • <no title>

    NAKAYAMA J.

    J. C. S. Perkin. Trans. I 1977, 468, 1977

    被引用文献1件

  • <no title>

    NARASO J.

    J. Am. Chem. Soc. 127, 10142, 2005

    被引用文献1件

  • <no title>

    NARASO J.

    J. Am. Chem. Soc. 128, 9598, 2006

    被引用文献1件

  • <no title>

    SAKAMOTO Y.

    J. Am. Chem. Soc. 126, 8138, 2004

    被引用文献1件

  • <no title>

    ANDO S.

    Chem. Mater. 17, 1261, 2005

    被引用文献1件

  • <no title>

    MENG H.

    J. Am. Chem. Soc. 127, 2406, 2005

    被引用文献1件

  • <no title>

    ANDO S.

    J. Am. Chem. Soc. 127, 5336, 2005

    被引用文献1件

  • <no title>

    FACCHETTI A.

    Chem. Mater. 16, 4715, 2004

    被引用文献1件

  • <no title>

    YAMASHITA Y.

    Proceeding of SPIE 6658, 66580N, 2007

    被引用文献1件

  • <no title>

    YAMAMOTO T.

    Chem. Mater. 16, 4616, 2004

    被引用文献1件

  • <no title>

    ANDO S.

    J. Am. Chem. Soc. 127, 14996, 2005

    被引用文献1件

  • <no title>

    KOJIMA T.

    Chem. Lett. 36, 1198, 2007

    被引用文献1件

  • <no title>

    ANDO S.

    J. Mater. Chem. 14, 1787, 2004

    被引用文献1件

  • <no title>

    ANDO S.

    Chem. Lett. 33, 1170, 2004

    被引用文献1件

  • <no title>

    ANDO S.

    Synth. Met. 156, 327, 2006

    被引用文献1件

  • <no title>

    ANDO S.

    J. Mater. Chem. 17, 553, 2007

    被引用文献1件

  • <no title>

    MAMADA M.

    Chem. Mater. 19, 5404, 2007

    被引用文献1件

  • <no title>

    JOHNSON J. R.

    J. Am. Chem. Soc. 92, 4046, 1970

    被引用文献1件

  • <no title>

    KUMAKI D.

    Appl. Phys. Lett. 90, 053506, 2007

    被引用文献1件

  • <no title>

    KONO T.

    Chem. Mater. 19, 1218, 2007

    被引用文献1件

  • <no title>

    AKHTARUZZAMAN M.

    Chem. Commun. 2005, 3183, 2005

    被引用文献1件

  • <no title>

    KOJIMA T.

    Chem. Commun. 2007, 1430, 2007

    被引用文献1件

  • <no title>

    ZAUMSEIL J.

    Nature Mater. 5, 69, 2006

    被引用文献1件

  • <no title>

    YOON M.-H.

    J. Am. Chem. Soc. 127, 1348, 2005

    被引用文献1件

  • <no title>

    NISHIDA J.

    Org. Lett. 6, 2007, 2004

    被引用文献1件

  • <no title>

    ISHI-I T.

    Org. Lett. 8, 585, 2006

    被引用文献1件

  • <no title>

    NISHIDA J.

    Chem. Lett. 35, 1236, 2006

    被引用文献1件

  • <no title>

    KLAUK H.

    J. Appl. Phys. 92, 5259, 2002

    DOI 被引用文献53件

  • High-Performance OTFTs Using Surface-Modified Alumina Dielectrics

    KELLEY T. W.

    J. Phys. Chem. B 107(24), 5877-5881, 2003

    DOI 被引用文献9件

  • <no title>

    KATZ H. E.

    Chem. Mater. 10, 457, 1998

    被引用文献3件

  • <no title>

    HALIK M.

    Adv. Mater. 15, 917, 2003

    被引用文献8件

  • <no title>

    PAPAVASSILIOU G. C.

    Chemica Scripta. 27, 265, 1987

    被引用文献1件

  • <no title>

    FACCHETTI A.

    Angew. Chem. Int. Ed. 39, 4547, 2000

    被引用文献10件

  • <no title>

    ITO K.

    Angew. Chem. Int. Ed. 42, 1159, 2003

    被引用文献1件

  • <no title>

    KITAMURA C.

    Chem. Mater. 8, 570, 1996

    被引用文献5件

  • <no title>

    MEIJER E. J.

    Nat. Mater. 2, 678, 2003

    被引用文献22件

  • <no title>

    WINKLER M.

    J. Am. Chem. Soc. 129, 1805, 2007

    被引用文献2件

  • <no title>

    NAKA S.

    Appl. Phys. Lett 76, 197, 2000

    被引用文献3件

各種コード

  • NII論文ID(NAID)
    10021175292
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    9504107
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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