ラジカル重合における精密制御 : 分子量, 立体構造, モノマー配列の制御 Precision Control in Radical Polymerization : Control of Molecular Weight, Stereochemistry, and Monomer Sequence

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著者

    • 上垣外 正己 KAMIGAITO Masami
    • 名古屋大学大学院工学研究科化学・生物工学専攻応用化学分野 Department of Applied Chemistry, Graduate School of Engineering, Nagoya University
    • 佐藤 浩太郎 SATOH Kotaro
    • 名古屋大学大学院工学研究科化学・生物工学専攻応用化学分野 Department of Applied Chemistry, Graduate School of Engineering, Nagoya University

抄録

This review article describes precision control of molecular weight, stereochemistry, and monomer sequence in radical polymerization. For molecular weight control, metal-catalyzed living radical polymerization, which is originated from metal-catalyzed Kharasch addition reaction, has been developed by designing the catalysts and has become applicable for a wide variety of vinyl monomers including methacrylates, acrylates, styrenes, acrylamides, vinyl acetate, etc. While the control of stereochemistry cannot be achieved by these metal catalysts, the stereochemical control based on the interaction of solvents or added Lewis acids has been combined with various living radical polymerizations for the simultaneous control of molecular weight and tacticity . A possibility of monomer sequence control has now been suggested by developing metal-catalyzed radical addition reaction to metal-catalyzed radical polyaddition of designed monomers for sequence-regulated vinyl polymers.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN  

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 66(6), 578-589, 2008-06-01 

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10021175478
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    9545027
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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