デザイン型フェノールの精密重合 : フェノール樹脂の新展開 Precision Polymerization of Designed Phenol : New Aspects of Phenolic Resin Chemistry

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Phenolic resin (novolac) has been industrially very important as a curing agent, epoxy resin, adhesive, etc. The materials based on the phenolic resin exhibit a good heat stability, mechanical property, and compatibility with polar polymers. These significant properties are derived from the rigid-rod-like main-chain structure (polyphenylenemethylene backbone) and the reactivities of the phenolic hydroxyl group. We now report functional poly(phenylenemethylene)s as a new class of phenolic resin prepared by the polycondensation of an alkoxybenzene derivative such as anisole and trimethoxybenzene with formaldehyde. The unique polymerization behaviors and properties of the obtained alkoxylated novolacs were observed due to the effect of protecting the phenolic hydroxyl group. Designed phenol (masked phenol derivative) is a versatile tool for design of high-performance phenolic resins and new class of aromatic polymers.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN  

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 66(7), 705-713, 2008-07-01 

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10021176152
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    9577749
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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