遷移金属触媒がもたらす高性能，高機能，新規ポリマー　　新規ポリオレフィンの精密合成を可能とする高性能遷移金属錯体触媒の設計・創製

• 野村 琴広

  奈良先端科学技術大学院大学 物質創成科学研究科

書誌事項

タイトル別名

• Design of Efficient Early Transition Metal Complex Catalysts for Synthesis of New Polyolefins by Precise Olefin Polymerization
• シンキ ポリオレフィン ノ セイミツ ゴウセイ オ カノウ ト スル コウセイノウ センイ キンゾク サクタイ ショクバイ ノ セッケイ ソウセイ

抄録

Selected successful examples for precise synthesis of new polyolefins by coordination insertion polymerization, especially by copolymerization of ethylene with new comonomer (s) using newly designed complex catalysts have been introduced. Efficient copolymerization of ethylene with styrene can be achieved by so called half-titanocene catalysts, and the ligand modification should play an essential key role especially for the efficient styrene incorporation. Efficient introduction of functional group into polyolefins has also been achieved by the (direct) copolymerization using nonbridged half-titanocenes, and a new synthetic strategy for precise, efficient synthesis of polyolefins containing polar functionalities with uniform compositions (as well as with uniform molecular weight distribution) under mild (environmentally benign) conditions can be demonstrated.

収録刊行物

• 日本ゴム協会誌

  日本ゴム協会誌 81 (10), 400-407, 2008

  一般社団法人 日本ゴム協会

キーワード

• Coordination Polymerization
• Titanium Complex
• Polyolefin
• Copolymerization
• Functionalization
• Catalyst

詳細情報

• CRID: 1390282681539556224
• NII論文ID: 10021873695
• NII書誌ID: AN00269207
• DOI: 10.2324/gomu.81.400
• COI: 1:CAS:528:DC%2BC3cXisVGhsr4%3D
• ISSN: 18840442
• ISSN: 0029022X
• NDL書誌ID: 9681707
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9681707
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可