加硫ゴムの伸張変形下におけるESR測定 ESR Measurements of Vulcanized Rubber under Tensile Deformation

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抄録

ESR measurements under tensile deformation of vulcanized rubber were carried out by the combination of homebuilt stretching machine with commercially available ESR spectrometer. The changes of radical concentrations during tensile deformation were successfully evaluated by this technique. It was found that the destruction and re-construction of crosslinking structure developed in the samples were well correlated with the changes of radical concentrations during tensile deformation. That is, the broken crosslinking structure by stretching was partly recovered in the sample crosslinked by sulfur. On the other hand, such behavior was minor in the sample crosslinked by peroxide.

収録刊行物

  • 日本ゴム協會誌  

    日本ゴム協會誌 81(11), 460-466, 2008-11-15 

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

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各種コード

  • NII論文ID(NAID)
    10021875224
  • NII書誌ID(NCID)
    AN00189720
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    0029022X
  • NDL 記事登録ID
    9719869
  • NDL 雑誌分類
    ZP17(科学技術--化学・化学工業--高分子化学・高分子化学工業--ゴム・プラスチックス)
  • NDL 請求記号
    Z17-125
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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