Synthesis of TiB2-TiC-Ti3SiC2 composites by reactive hot pressing of B4C-SiC-Ti powder mixtures

• Taimatsu Hitoshi

  Department of Materials Science and Engineering, Faculty of Engineering and Resource Science, Akita University

• Sugiyama Shigeaki

  Akita Prefectural Research and Development Center

• Koseki Shuhou

  Department of Materials Science and Engineering, Faculty of Engineering and Resource Science, Akita University

書誌事項

タイトル別名

• Synthesis of TiB<SUB>2</SUB>-TiC-Ti<SUB>3</SUB>SiC<SUB>2</SUB> Composites by Reactive Hot Pressing of B<SUB>4</SUB>C-SiC-Ti Powder Mixtures

抄録

TiB₂-TiC-Ti₃SiC₂ composites were reaction-sintered from B₄C-xSiC-(3+2x)Ti (x=0 to 1) powder mixtures using reactive hot pressing, and the phase relation of reaction products and sintering behavior were investigated. The reaction B₄C+xSiC+(3+2x)Ti→2TiB₂+(1−x)TiC+xTi₃SiC₂ proceeded fundamentally during hot pressing. Although the reaction demands no production of TiC phase at x=1, TiC phase was formed due to the nonstoichiometry of TiC and Ti₃SiC₂ phases produced. The hot-pressed composites containing the layered compound Ti₃SiC₂ had no preferential texture. Both TiB₂ and TiC were first produced near 960°C during heating, and then Ti₃SiC₂ near 1200°C. The product Ti₃SiC₂ contributed effectively to the densification of the composites above 1450°C.

収録刊行物

• MATERIALS TRANSACTIONS

  MATERIALS TRANSACTIONS 49 (10), 2335-2340, 2008

  公益社団法人 日本金属学会

キーワード

• titanium boride
• titanium carbide
• titanium silicon carbide
• reaction sintering
• solid state reactions

詳細情報

• CRID: 1390001204250343552
• NII論文ID: 10024326235
• NII論文ID: 130004453810
• NII書誌ID: AA1151294X
• DOI: 10.2320/matertrans.mra2008174
• ISSN: 13475320
• ISSN: 13459678
• NDL書誌ID: 9663470
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9663470
• Web Site: https://www.jstage.jst.go.jp/article/matertrans/49/10/49_MRA2008174/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可