Thermotropic Columnar Liquid Crystal of a <i>C</i>6-Symmetric Hydrogen-bonded Hexakis(phenylethynyl)benzene Derivative with Amino Acid Pendant Groups

• Koichi Sakajiri

  Department of Chemistry, Faculty of Engineering, Gifu University

• Hironori Yoshida

  Department of Chemistry, Faculty of Engineering, Gifu University

• Keiichi Moriya

  Department of Chemistry, Faculty of Engineering, Gifu University

• Shoichi Kutsumizu

  Department of Chemistry, Faculty of Engineering, Gifu University

抄録

The thermotropic liquid crystalline C6-symmetric hydrogen-bonded disk-like molecule has been obtained in a hexakis(phenylethynyl)benzene derivative bearing chiral didodecyl l-glutamates, which forms a hexagonal columnar phase over a wide temperature range including room temperature, where each π–π stacking between the large central cores is reinforced by the six intermolecular hydrogen bonds.

収録刊行物

• Chemistry Letters

  Chemistry Letters 38 (11), 1066-1067, 2009-10-10

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694087931392
• NII論文ID: 10025548055
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2009.1066
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/38/11/1066/55600435/cl.2009.1066.pdf
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