樹木状多分枝ポリマーの精密合成

• 平尾 明

  東京工業大学大学院理工学研究科有機・高分子物質専攻

• 渡部 拓海

  東京工業大学大学院理工学研究科有機・高分子物質専攻

• Hee–Soo Yoo

  Graduate School of Science and Engineering, Tokyo Institute of Technology

書誌事項

タイトル別名

• Precise Synthesis of Dendrimer-Like Hyperbranched Polymers
• ジュモクジョウ タブンシ ポリマー ノ セイミツ ゴウセイ

抄録

Dendrimer–like hyperbranched polymers (DBP)s have recently appeared as a new class of hyperbranched polymers. Although (DBP)s resemble dendrimers in branched architecture, they are composed of polymer chains between junctions and, accordingly, much higher in molecular weight and much larger in molecular size than dendrimers. Because of their specific hyperbranched structures and nano–size globular molecular shapes, (DBP)s have attracted much attention due to specialty functional materials and supra–structured nano–materials with many potential applications. In this review article, precise syntheses of DBP by previously reported procedures and recently developed new methodology based on “arm–first” divergent approach are highlighted. Furthermore, the possible synthesis of various (DBP)s having different branched architectures and polymer chains are introduced. Finally, their solution properties, sizes, and shapes are discussed.

収録刊行物

• 有機合成化学協会誌

  有機合成化学協会誌 67 (10), 1033-1043, 2009

  公益社団法人 有機合成化学協会

キーワード

• dendrimer–like hyperbranched polymer
• “arm–first” divergent approach
• iterative methodology
• living anionic polymer
• generation–based block copolymer
• precise synthesis

詳細情報

• CRID: 1390001205311988096
• NII論文ID: 10025644826
• NII書誌ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.67.1033
• COI: 1:CAS:528:DC%2BD1MXht1Kqt73M
• ISSN: 18836526
• ISSN: 00379980
• NDL書誌ID: 10385136
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I10385136
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可